Stabilized fracture fluid and crosslinker therefor

摘要

Various organometallic crosslinkers containing titanium or zirconium atoms in the +4 oxidation (valence) state have been used to crosslink solvatable polysaccharides (e.g., hydroxypropyl guar) in aqueous media. The crosslinked gels are useful as fracturing fluids. Aqueous solutions of the organometallic crosslinkers are stabilized against deterioration upon storage by adding an alkanolamine (e.g., triethanolamine). Additionally, the alkanolamines also stabilize the crosslinked gels against shear degradation at elevated temperatures.