发明名称 PRODUCTION OF POLYMERIZABLE VINYL COMPOUND HAVING POLYTHIOETHER SKELETON
摘要 PURPOSE:To obtain the titled compound of good storage stability, capable of giving cured products with uniformity and high oxidation stability, by addition reaction, in the presence of a base catalyst, between each specific polyene compound and polythiol compound in the total number ratio of the vinyl group to the SH group higher than a specified value. CONSTITUTION:The objective polymerizable vinyl compound can be obtained by addition reaction, in the presence of a base catalyst, between (A) a polyene compound of formula A-Xm [X is of formula I (R<1> is H or CH3), etc.; m is integer >=2; A is polyvalent hydrocarbon group, of formula II (R<2> is H, OH or aliphatic hydrocarbon residue; R<3> is hydrocarbon residue which may contain halogen; q is integer >=1), etc.] or formula Yn-D-Xp (Y is group of formula III; n and p are each integer >=1; D is the same kind as A) and (B) a polythiol compound of formula R<4>-(SH)r (R<4> is polyvalent hydrocarbon; r is integer 2-4) under such a condition that the total number ratio of the vinyl group to the thiol group is >=2.
申请公布号 JPS63238132(A) 申请公布日期 1988.10.04
申请号 JP19870070471 申请日期 1987.03.26
申请人 SHOWA DENKO KK 发明人 TAKENOSHITA YOUICHIROU;YOSHIDA HARUO
分类号 C08G75/04;C08F290/00;C08F299/00;C08G75/02 主分类号 C08G75/04
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