发明名称 OPTICALLY ACTIVE LIQUID CRYSTAL COMPOUND CONTAINING ORTHO-CYANO-BENZENE SKELETON
摘要 NEW MATERIAL:A compound expressed by formula I [R<1> is 2-18C alkyl; R<2> is 1-20C alkyl, alkyloxy, H, halogen or cyano; A is -COO- or -OCO-; B and C are both single bond, formula II, formula III (X is H, halogen or cyano), etc.; l, m and n are 0 or 1]. EXAMPLE:(S)-3-Cyano-4-(2'-methylbutyl)benzoic acid 4-octyloxy-4'-biphenyl ester. USE:A liquid crystal display element which is a chiral crystal composition having an optically active group and capable of constituting a light switching element by using the composition. The aimed compound is a liquid crystal compound having large value of spontaneous polarization. PREPARATION:A compound expressed by formula IV is brominated in the presence of a catalyst and the brominated compound is then reacted with phenols is order to carry out esterification to afford a compound expressed by formula V, which is then reacted with a cyanidating agent to give the compound expressed by formula I.
申请公布号 JPS63233966(A) 申请公布日期 1988.09.29
申请号 JP19870067097 申请日期 1987.03.20
申请人 CHISSO CORP 发明人 MIYAZAWA KAZUTOSHI;INUKAI TAKASHI;INOUE HIROMICHI;SAITO SHINICHI;ONO KOJI
分类号 C07D213/84;C07C67/00;C07C253/00;C07C253/14;C07C255/50;C07C255/55;C07C255/57;C07D213/06;C07D213/55;C07D213/61;C07D213/65;C07D237/08;C07D237/14;C07D237/24;C07D239/26;C07D239/28;C07D239/34;C09K19/06;C09K19/12;C09K19/20;C09K19/30;C09K19/34;C09K19/42;C09K19/44;G02F1/13 主分类号 C07D213/84
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