发明名称 FREMGANGSMAATE VED FREMSTILLING AV EN HYDROGENERINGSKATALYSATOR, SAMT ANVENDELSE DERAV.
摘要 A RH-contg. homogeneous hydrogenation catalytic system is p prepd. by reacting rhodium trinitrate, hydrazine and tert. phosphine in a solvent under the inert condition. Tert. phosphine is opt. triphenylphosphine hydrazine is opt. hydrazine or its hydrate, and the solvent is opt. C1-4 aliphatic alcohol. The catalyst is use in the stereoselective hyrogenation of methacycline for oxycycline preparation.
申请公布号 NO881313(A) 申请公布日期 1988.09.26
申请号 NO19880001313 申请日期 1988.03.24
申请人 PLURICHEMIE ANSTALT 发明人 HEGGIE, WILLIAM;PAGE, PHILIP RONALD;VILLAX, IVAN;GHATAK, INDIRA;HURSTHOUSE, MICHAEL BARRY
分类号 B01J23/46;B01J;B01J31/00;B01J31/12;B01J31/18;B01J31/24;C07B35/00;C07B35/02;C07C;C07C5/03;C07C5/05;C07C237/26;C07C237/48;C07F;C07F15/00 主分类号 B01J23/46
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