摘要 |
A solution process, and a catalyst therefor, for the preparation of high molecular weight polymers of alph-olefins viz. homopolymers of ethylene and copolymers of ethylene and C3-C12 alpha-olefins, is disclosed. The process is operated under solution polymerization conditions at 105 DEG -320 DEG . The catalyst is obtained from titanium tetrahalides, vanadium oxytrihalides and organoaluminum compounds, in which an admixture of catalyst components is heat-treated at 150 DEG -320 DEG C., and activated with an aluminoxane. The catalyst has good activity and the polymer obtained has improved color.
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