摘要 |
A process of producing a room temperature-stable solvent solution from a high molecular weight dimethyl terephthalate solid polyester is disclosed in which the polyester is incorporated into a hot melt of an hydroxy-functional linear polyester having an hydroxy number of at least about 20, an acid number of less than about 30 and a molecular weight in the range of 1,000 to 10,000. This forms a molten mixture containing from about 20% to about 55% of terephthalate polyester which is maintained as a hot melt until a sample of the melt forms a clear to slightly cloudy solution in a 50% mixture thereof with 2-ethoxy diethanol glycol acetate. The reacted hot melt is then mixed with an organic solvent to form a solution which is useful in thermosetting solvent solution coating compositions. Aqueous coating compositions may be made using water having dispersed therein a salt of an epoxy phosphate with a volatile base and having stably dispersed therein the aforesaid reacted hot melt after the same is mixed with a water-miscible organic solvent to form a solution which is dispersed in the aqueous medium and cured with a curing agent reactive with hydroxyl functionality. |