发明名称 POLYMERIZATION OF ALPHA-OLEFIN
摘要 PURPOSE:To produce an alpha-olefin polymer superior in stereoregularity at a relatively low temperature, by supplying specific solid catalyst component to heated system, in which an organic A1 compound and an alpha-olefin are present, to polymerize the monomer. CONSTITUTION:A solid material obtained by adding, to a suspension of 1g of dialkoxymagnesium in an aromatic hydrocarbon at ordinary temperatures, 0.1g or more of TiCl4 and 0.01-2g of an aromatic dicarboxylic diester to react at 80-135 deg.C, is reacted with TiCl4 of 100hr. or less to produce a solid product. 1g of the solid product is then contacted with 0.1-10g of a Si compound of the formula [wherein R is (cyclo)alkyl, vinyl or aryl; R' is alkyl; and 0<=m<=4] followed by contact with 0.1-10g of an organic A1 compound to produce a solid catalyst component. Subsequently, to a reaction system maintained at 70-90 deg.C in which at least an organic A1 compound and an alpha-olefin monomer are present, the solid catalyst component to polymerize the alpha-olefin monomer is supplied.
申请公布号 JPS63182306(A) 申请公布日期 1988.07.27
申请号 JP19870012263 申请日期 1987.01.23
申请人 TOHO TITANIUM CO LTD 发明人 TERANO MINORU;SOGA HIROKAZU;INOUE MASUO
分类号 C08F4/64;C08F4/60;C08F4/658;C08F10/00 主分类号 C08F4/64
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