| 摘要 |
A process is provided for the coloration of a preformed polyester resin shaped article having improved dye migration properties, which comprises: (a) coloring said article with a coloring agent in an amount sufficient to provide coloration to said shaped article; said coloring agent having the formula R-(polymeric constituent-X)n wherein R is an organic dyestuff radical; the polymeric constituent is selected from polyalkylene oxides and copolymers of polyalkylene oxides in which the alkylene moiety of the polymeric constituent contains 2 or more carbon atoms and such polymer constituent has a molecular weight of from about 132 to about 5000; andn is an integer of from 1 to about 12; and X is selected from -OH, -NH2, -SH, -OCOR1, -CO2H, -CO2R1, -SO3H, -SO3R1 phosphate, phosphonite, urea, urethane, alkoxyl and alkoxide, wherein R1 is a lower alkyl group containing from 1 to about 6 carbon atoms; and (b) grafting said coloring agent to said article by heating said article to a temperature below a temperature at which said article will melt, but to a high enough temperature and for a period of time sufficient to achieve grafting of said coloring agent to said article.
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