发明名称 Esters of 3-tert-butyl- or 3-tert-butyl-5-alkyl-4-hydroxyphenyl(alkane)carboxylic acids with ethoxylates of monofunctional thiophenols and thiols, process for their preparation and their use as stabilisers
摘要 Esters of 3-tert-butyl- or 3-tert-butyl-5-alkyl-4-hydroxyphenyl(alkane)carboxylic acids of the formula I <IMAGE> where R1 = C(CH3)3, R2 = C1- to C4-alkyl or H, preferably -C(CH3)3, m = 0 to 4, preferably 2, with ethoxylates of monofunctional thiophenols or of cycloaliphatic or aromatic-containing monofunctional thioalcohols of the formulae II to V <IMAGE> where l, m, n and o = 1 to 3, preferably 1, m + o = 5, p = 0 to 7, preferably 1, R = H, C1- to C4-alkyl or aryl, R3, R4 and R5 = H, C1- to C4-alkyl, C5- to C12-cycloalkyl, aryl or halogen (only in the formulae II to IV). To prepare these esters, the 3-tert-butyl- or 3-tert-butyl-5-alkyl-4-hydroxyphenyl(alkane)carboxylic acid or their derivatives are esterified with the ethoxylates of the thiophenols or thioalcohols or esterified in the presence of alkaline or neutral catalysts known per se. The esters according to the invention are used for the stabilisation of polymers.
申请公布号 DE3639400(A1) 申请公布日期 1988.05.26
申请号 DE19863639400 申请日期 1986.11.18
申请人 HUELS AG 发明人 KUEPPER,FRIEDRICH-WILHELM,DR.;VOGES,HEINZ-WERNER,DR.;PAETZOLD,WERNER;SCHAAF,RICHARD,DR.
分类号 C08K5/37;(IPC1-7):C07C149/32;C07C149/273;C07C149/26 主分类号 C08K5/37
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