发明名称 ESTER DERIVATIVE OF 2-CYANO-1-ALKANOL
摘要 NEW MATERIAL:A compound expressed by formula I (R<1> is 1-20C alkyl or alkoxy; R<2> is 1-18C alkyl; m is 0 or 1; * is asymmetric carbon). EXAMPLE:(+ or -)-4-(2'-Cyano-hexyloxycarbonyl)-phenyl-4'-octyloxy-4-biphenylcarboxyla te. USE:An ingredient of ferroelectric liquid crystal composition, suitable as the ingredient carrying spontaneous polarization value of the ferroelectric liquid crystal composition. PREPARATION:A compound obtained from an optically active alpha-amino acid expressed by formula I is esterified and a hydroxyl group of the resultant compound is protected with tetrahydropyranyl, then reduced, esterified, deprotected and tosylated to afford a compound expressed by formula II, which is then substituted with a cyano group to provide a compound expressed by formula I (m is 0).
申请公布号 JPS63119449(A) 申请公布日期 1988.05.24
申请号 JP19860263605 申请日期 1986.11.05
申请人 CHISSO CORP 发明人 SAITO SHINICHI;INOUE HIROMICHI;MIYAZAWA KAZUTOSHI;ONO KOJI;SHIODA MAKOTO
分类号 C09K19/12;C07C67/00;C07C253/00;C07C255/14;C09K19/20;C09K19/54;G02F1/13 主分类号 C09K19/12
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