发明名称 Process for the preparation of alpha - beta unsaturated alcohols
摘要 The invention relates to a process for the preparation of alpha - beta unsaturated alcohols of the formula <IMAGE> where R1, R2 and R3, which may be equal or different, represent phenyl, optionally substituted with one or more alkyl and/or alkoxy groups, the total number of C atoms of these substituents being at most 5, or hydrogen or an alkyl group with 1-10 C atoms, with at least one of the groups R1, R2 and R3 representing the optionally substituted phenyl group, by hydrogenation in the liquid phase of the aldehyde corresponding with the desired alcohol, this being effected in the presence of a platinum-containing catalyst and of an alkali metal hydroxide and/or an alkali metal alkoxide as promotor, wherein platinum-on-graphite is used as catalyst.
申请公布号 US4745234(A) 申请公布日期 1988.05.17
申请号 US19870086788 申请日期 1987.08.19
申请人 STAMICARBON B.V. 发明人 VAN DE MOESDIJK, CORNELIS G. M.;BOSMA, MARCEL A. R.
分类号 C07C43/178;B01J23/00;B01J31/00;C07B61/00;C07C29/141;C07C41/00;C07C67/00;(IPC1-7):C07C29/14 主分类号 C07C43/178
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