Process for purification of the off-gases resulting from the production of benzoyl chloride from phosgene

摘要

A process for purification of the off-gases resulting from the production of benzoyl chloride by phosgenation of benzoic acid from phosgene comprising recovery of phosgene from said off-gases by means of a selective absorbent, i.e. benzoyl chloride at a temperature within the range of from 1 DEG to 40 DEG C. The recovered phosgene is recycled to the production of benzoyl chloride. The process is technologically simple, it makes possible to purify the off-gases without decomposition of phosgene thus preventing pollution of the environments; it also makes possible to simplify utilization of hydrogen chloride contained in the off-gases and, thereby, simplify preparation of commercial hydrochloric acid.