发明名称 Procédé de déprotection des esters et éthers allyliques.
摘要 A process is disclosed for the deprotection of allylic esters and ethers. The process comprises reacting an allyl ester of a carboxylic acid or an allyl ether of a phenol with pyrrolidine or piperidine and a catalytic amount of an organic-soluble palladium complex having a coordinating phosphine ligand to cleave the allyl moiety. The resultant carboxylic acid or phenol is then recovered.
申请公布号 OA8340(A) 申请公布日期 1988.02.29
申请号 OA19860058874 申请日期 1986.06.06
申请人 BRISTOL-MYERS COMPANY 发明人 ROBERT DEZIEL
分类号 C07D487/04;B01J31/00;B01J31/24;C07B31/00;C07B41/02;C07B41/08;C07B51/00;C07B61/00;C07C27/00;C07C27/02;C07C37/055;C07C39/04;C07C51/00;C07C51/09;C07C57/44;C07C63/04;C07C67/00;C07D477/00;C07D477/08;C07D499/00;C07D499/04;C07D499/08;C07D499/46;C07D501/02;C07D501/04;C07D501/30 主分类号 C07D487/04
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