Polyzwitterionic acid antiscalant compound

摘要

The polyzwitterionic acid antiscalant is an antiscalant for use in desalination plants and the like for inhibiting CaSO4 and SO42− scale precipitation. The polyzwitterionic acid (PZA) antiscalant has the following structural formula:;;In order to make the PZA antiscalant, N-carboethoxymethyl-3-(N,N-diallylamino)propanesulfonate, a zwitterionic monomer, is cyclopolymerized in aqueous solution using tert-butyl hydroperoxide (TBHP) to make an intermediate polyzwitterion (PZ). Acidic hydrolysis of the ester groups of the PZ is performed to produce the PZA antiscalant. Evaluation of the antiscalant properties of the PZA antiscalant using concentrated brines revealed that the PZA antiscalant, at a concentration of 10 ppm, is very effective in inhibiting the formation of calcium sulfate scale, particularly in reverse osmosis plants.

主权项

1. A method of making a polyzwitterionic antiscalant compound, comprising the steps of:
cyclopolymerizing N-carboethoxymethyl-3-(N,N-diallylamino)propanesulfonate monomer in aqueous solution using tert-butyl hydroperoxide as an initiator to form a polyzwitterion having the structural formula:  wherein the step of cyclopolymerizing comprises the steps of:
preparing a solution of the monomer in 1M NaCl aqueous solution;adding the tert-butyl hydroperoxide initiator to the solution;stirring the solution in a closed vessel at a temperature of 90° C. for a period of 48 hours;cooling the solution;dialyzing the cooled solution against deionized water for a period of 48 hours;removing unreacted monomer and NaCl from the solution; andfreeze-drying the solution to produce the polyzwitterion; and performing acid hydrolysis on ester groups of the polyzwitterion to form a polyzwitterionic acid having the structural formula:  wherein the step of performing acid hydrolysis comprises the steps of:
preparing a solution of the polyzwitterion in HCl;hydrolyzing the solution in a closed vessel at a temperature of 53° C. for a period of 48 hours;cooling the hydrolyzed solution to room temperature;dialyzing the cooled, hydrolyzed solution against deionized water for a period of 24 hours; andfreeze-drying the dialyzed solution to produce the polyzwitterionic acid.