发明名称 |
PRODUCTION OF HYDROGEN FOR DISTRIBUTED FUEL CELL |
摘要 |
PURPOSE:To easily produce hydrogen for distributed fuel cell, by contacting kerosene containing a specific amount of sulfur with an Ni-based adsorbent under high pressure and temperature to remove the sulfur, adding water to the reaction system and carrying out reformation reaction with an Ni catalyst. CONSTITUTION:JIS No.1 kerosene containing 10-150wt.ppm of sulfur is used as a raw material. The kerosene is brought into contact with an Ni-based adsorbent having a surface area of >=50m<2>/g under atmospheric pressure - 10kg/cm<2>.G at 150-250 deg.C in the absence of hydrogen or in the presence of <=0.2mol of hydrogen based on 1mol of kerosene. The Ni-based adsorbent is produced by supporting >=50wt% Ni (in terms of metal) on a carrier. The residual sulfur content in the kerosene is decreased to <=0.5wt.ppm by this treatment. The treated kerosene is added with a required amount of water and the mixture is introduced into a steam reformer filled with a reforming catalyst having an Ni-content of >=5wt%. Hydrogen gas for distributed fuel cell can be produced by the reformation reaction in the steam reformer. |
申请公布号 |
JPS6335403(A) |
申请公布日期 |
1988.02.16 |
申请号 |
JP19860175322 |
申请日期 |
1986.07.25 |
申请人 |
NIPPON OIL CO LTD |
发明人 |
FUJIMUNE TOKUO;HAYASHI MASAYUKI;NOMURA SOICHI |
分类号 |
B01J20/02;C01B3/38;H01M8/06 |
主分类号 |
B01J20/02 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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