发明名称 |
PROCESS FOR PRODUCING METHACRYLIC ACID AND CATALYSTS FOR THE PROCESS. |
摘要 |
<p>A catalyst for the production of methacrylic acid by the oxidation of methacrolein with oxygen in the gas phase has the formula: PaMobVcFedCueZfXgYhOi where X is K, Rb, Cs and/or Tl- Y is Te, La, B, Ag, Cr, Mg and/or Ba; Z is Zr or Sb; a = 0.3-4; b = 12; c = 0.01-3; d = 0.01-4; e = 0.01-3; f = 0.01-3; g = 0.01-3; h = 0.001-5; i is the number of oxygen atoms required to satisfy the valencies of the other elements present. The catalyst is prepd. by pyrolysis of a mixt. of cpds. of the elements present in appropriate ratio. The prepn. of methacrylic acid is carried out by passing methacrolein (1-20% by wt.) and oxygen (0.3-4 moles per mole of methacrolein) in an inert carrier gas (such as nitrogen, steam or carbon dioxide) over the catalyst at 230-450 deg. C.</p> |
申请公布号 |
EP0253896(A1) |
申请公布日期 |
1988.01.27 |
申请号 |
EP19870900686 |
申请日期 |
1987.01.06 |
申请人 |
MITSUBISHI RAYON CO. LTD. |
发明人 |
OH-KITA, MOTOMU;KATO, MASAAKI;KOBAYASHI, MASAO |
分类号 |
B01J23/28;B01J27/198;B01J27/199;C07C51/235;C07C51/25;C07C57/04;C07C57/055;(IPC1-7):B01J27/198 |
主分类号 |
B01J23/28 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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