摘要 |
Lubricating and functional fluid compositions having improved extreme pressure properties and high temperature stability. The compositions contain at least one ammonium or metal salt of at least one phosphorus- and sulfur-containing composition and at least one soluble nitrogen-containing composition. More particularly, the oil-based lubricating and functional fluid compositions of the present invention comprise a major amount of oil and a minor amount of (A) at least one amine or metal salt of at least one monothiophosphoric acid of formulae (I) or (II) or mixtures thereof wherein R<1> and R<2> are each independently hydrocarbyl groups, X is a metal or an ammonium group, and when X is a metal, n is an integer equal to the valence of the metal, and when X is an ammonium group, n=1, and (B) at least one soluble nitrogen-containing composition prepared by the reaction of a hydrocarbon-substituted succinic acid-producing compound with at least about one-half equivalent, per equivalent of acid producing compound, of an amine containing at least one hydrogen attached to a nitrogen atom. Preferably, the amine salts of the phosphoric acids utilized in the lubricating compositions of the present invention are derived from primary or tertiary amines, and the soluble nitrogen-containing compositions (B) also contain boron. The lubricating compositions of the present invention are particularly useful as lubricating oils or greases. Aqueous systems, and a method for preparing O-hydrocarbyl-S-hydrocarbyl monothiophosphates also are described herein. |