发明名称 Preparation of alkenylaromatics
摘要 Alkenylaromatics I <IMAGE> I where R1 is C1-C6-alkyl, R2 is H or C1-C10-alkyl and Ar is aryl, are prepared by reacting a vinylaromatic II <IMAGE> II with an alpha -olefin III H2C=CHR2 III in the presence of a nickel-containing catalyst system consisting of (a) a nickel(II) salt of a carboxylic acid, of an alcoholate or of a phenolate, (b) a phosphite or phosphine and (c) an organoaluminum compound V <IMAGE> V where R6 is C1-C12-alkyl, X is halogen and n is 1 or 2, or a mixture of compounds V.
申请公布号 US4709109(A) 申请公布日期 1987.11.24
申请号 US19860917906 申请日期 1986.10.10
申请人 BASF AKTIENGESELLSCHAFT 发明人 SPERLING, KARIN;FISCHER, MARTIN
分类号 C07C2/72;B01J31/00;B01J31/04;B01J31/14;B01J31/18;B01J31/22;B01J31/24;C07B61/00;C07C1/00;C07C2/04;C07C15/44;C07C67/00;(IPC1-7):C07C15/46 主分类号 C07C2/72
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