发明名称 Carbonylation of mercaptans
摘要 Thioesters of the formula RCOSR are produced from a mercaptan of the formula RSH wherein R is a benzylic, aromatic or aliphatic moiety by reacting the mercaptan with carbon monoxide in the presence of a polyunsaturated olefinic hydrocarbon and as catalyst a metal component selected from iron, cobalt, nickel, molybdenum, ruthenium, rhodium and iridium, the metal component being in free or combined form.
申请公布号 US4705880(A) 申请公布日期 1987.11.10
申请号 US19860870187 申请日期 1986.06.03
申请人 THE BRITISH PETROLEUM COMPANY P.L.C. 发明人 ALPER, HOWARD;SMITH, DAVID J. H.
分类号 C07B61/00;B01J31/00;B01J31/02;C07C;C07C67/00;C07C325/00;C07C327/02;C07C327/06;C07C327/20;C07C327/26;(IPC1-7):C07C153/017;C07C153/023 主分类号 C07B61/00
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