| 发明名称 |
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| 摘要 |
A process for the preparation of enamines or imines by isomerization of allylamine derivatives is described. Allylamine derivatives represented by formula (I): <IMAGE> (I) are isomerized using as a catalyst a rhodium complex represented by formula (IV): [Rh(olefin)L]+ X-(IV) to form enamines or imines represented by, respectively, formula (II) or formula (III): <IMAGE> (II) or <IMAGE> (III) All of the symbols in the above formulae are as described. These enamines or imines are useful intermediates for the preparation of a number of organic compounds. |
| 申请公布号 |
JPS6251945(B2) |
申请公布日期 |
1987.11.02 |
| 申请号 |
JP19810102039 |
申请日期 |
1981.06.30 |
| 申请人 |
TAKASAGO PERFUMERY CO LTD |
发明人 |
OOTSUKA SAINOSUKE;TANI KAZUHIDE;YAMAGATA TSUNEAKI;AKUTAGAWA SUSUMU;KUMOBAYASHI HIDENORI;YAGI MISAO |
| 分类号 |
C07D295/02;B01J31/00;C07B61/00;C07C45/51;C07C45/56;C07C67/00;C07C209/00;C07C209/68;C07C211/21;C07C211/25;C07C211/28;C07C211/35;C07C213/00;C07C213/08;C07C215/22;C07C241/00;C07C251/02;C07C251/04;C07D295/023 |
主分类号 |
C07D295/02 |
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