发明名称 PRODUCTION OF ACRYLIC ACID OF METHACRYLIC ACID ALKYLKAMINOALKYL ESTER
摘要 PURPOSE:To obtain the titled compound useful as a monomer, etc., readily in high yield and in high purity, by using an alkali metallic phosphate as a catalyst and subjecting (meth)acrylic acid methyl ester and an alkylamino-alcohol to ester exchange reaction. CONSTITUTION:(meth)acrylic acid methyl ester shown by formula I and an alkylkamino-alcohol such as a compound shown by formula II shown by formula III (R1 is H or 1-6C alkyl; R2 is 1-6C alkyl; n is 2-6) are subjected to ester exchange reaction by the use of an alkali metallic phosphate selected from sodium phosphate, potassium phosphate, rubidium phosphate and phosphate hydrates thereof preferably dissolved in methanol as a catalyst preferably at 50-120 deg.C preferably 10-760mmHg preferably while removing methanol out of the reaction system to give the aimed compound such as a compound shown by formula IV, etc. USE:An improver for dyeing fibers, plastic antistatic agent, etc.
申请公布号 JPS62230755(A) 申请公布日期 1987.10.09
申请号 JP19860072464 申请日期 1986.04.01
申请人 MITSUI TOATSU CHEM INC 发明人 ITOI AKIRA;YAMADA ATSURO;MURANAKA HIDEKAZU
分类号 C07B61/00;B01J27/00;B01J27/18;C07C67/00;C07C213/00;C07C213/06;C07C219/08 主分类号 C07B61/00
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