发明名称 METHOD FOR PREVENTING PRECIPITATION OF CATALYST
摘要 PURPOSE:To prevent the precipitation of a catalyst without imparting effect to catalytic activity, by adding a specific amount of 10-20 C aliphatic alcohol, etc. to a catalyst system containing an Ni salt of an organic acid or an Ni- complex compound and tirialkyl aluminum, etc. CONSTITUTION:A catalyst system containing a Ni salt of an organic acid or Ni-complex compound, trialkyl aluminum, a trivalent phosphoric compound represented by formula I, II or III (wherein R<1>, R<2> and R<3> are an alkyl group, a cycloalkyl group or a phenyl group) and fluorinated isopropanol represented by formula IV [wherein (m) and (n) are an integer of 4<=m+n] is prepared. 0.05-0.8mol times based on trialkyl aluminum of 10-20 C aliphatic alcohol, carboxylic acid or ester thereof is added to said catalyst system to prevent the precipitation of a catalyst.
申请公布号 JPS62221450(A) 申请公布日期 1987.09.29
申请号 JP19860064531 申请日期 1986.03.22
申请人 SUMITOMO CHEM CO LTD 发明人 SATO HIROSHI;IKIMI KIYOSHI;TOSHIMA HIDETO;TAKAHASHI SHIYOU
分类号 B01J31/14;B01J31/22;B01J31/24;C07C2/24;C07C11/02 主分类号 B01J31/14
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