发明名称 OPTICAL RESOLUTION OF SULFOXIDE
摘要 PURPOSE:To optically resolve a sulfoxide useful as an intermediate for organic synthesis by a simple method, by carrying out the optical resolution of an enantiomer mixture of a sulfoxide derivative using a readily available and inexpensive polysaccharide derivative as a separating agent. CONSTITUTION:An enantiomer mixture of a solfoxide derivative having a partial skeleton expressed by the formula is optically resolved using a separating agent, e.g. cellulose tribenzoate, containing a polysaccharide derivative as an active ingredient by chromatography. The separating agent for the chromatography is preferably granular and the size thereof is preferably 1mum-10mm in a porous form.
申请公布号 JPS62198657(A) 申请公布日期 1987.09.02
申请号 JP19860041109 申请日期 1986.02.26
申请人 DAICEL CHEM IND LTD 发明人 SHIBATA TORU
分类号 C07B57/00;B01J20/291;C07B31/00;C07C67/00;C07C313/00;C07C319/28;C07C323/65;G01N30/88 主分类号 C07B57/00
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