Oxidation of carbonaceous material

摘要

The gaseous effluent from oxidation of organic material with oxygen-rich gas, which effluent contains CO2 (and possible CO) and unreacted residual oxygen, is compressed and charged to a PSA system for selective removal of the COx, the thus purified oxygen-rich product from the PSA system being recycled to the oxidation reaction. In the PSA system comprised of a plurality of adsorption columns operated in parallel, each column in turn undergoes the steps of: (1) selective adsorption of CO2 from the feed gas; (2) depressuring to near ambient level; (3) purging with air to remove sorbed CO2; and (4) repressuring with part of the recycled effluent from step (1).