发明名称 |
A CATALYST FOR ISOMERIZATION REACTION |
摘要 |
The present invention relates to a catalyst for the isomerization reaction from quadricyclanes to norbornadienes in a conversion system from light energy to heat energy which comprises cyclopropenylidene palladium complex represented by the formula, <IMAGE> wherein R represents hydrogen atom, a lower alkyl or cyano group and X represents a halogen atom, and further relates to a fixed catalyst for the isomerization reaction from quadricyclanes to norbornadienes in a conversion system from light energy to heat energy which is obtained by adsorption-fixing a porphyrin Co(II) complex represented by the formula, <IMAGE> wherein R2 represents a lower alkyl group and R3 represents a hydroxycarbonyl lower alkyl group, to a modified inorganic carrier in which a polyamine sulfone comprising a recurring unit represented by the formula, <IMAGE> wherein R1 represents a lower alkyl group and X represents a halogen atom, has been adsorbed on a solid inorganic carrier. |
申请公布号 |
DE3464897(D1) |
申请公布日期 |
1987.08.27 |
申请号 |
DE19843464897 |
申请日期 |
1984.02.17 |
申请人 |
SUMITOMO CHEMICAL COMPANY, LIMITED |
发明人 |
YOSHIDA, ZENICHI;MIKI, SADAO |
分类号 |
B01J31/18;B01J31/22;B01J31/28;C07C5/31;C07F15/00;(IPC1-7):C07C5/31;B01J31/16 |
主分类号 |
B01J31/18 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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