发明名称 Process for the preparation of alpha-amino alpha-hydrogen carboxylic acid amides.
摘要 The invention relates to a process for the preparation of alpha -amino- alpha -hydrogen carboxylic acid amides of the formula <CHEM> where R1 represents alkyl, alkaryl, aryl, alkenyl, heteroalkyl or heteroaryl, whether or not substituted, by conversion of the corresponding amino nitriles and is characterized in that the conversion takes place in the presence of hydrogen peroxide and ammonia. By preference use is made of 2-6 moles hydrogen peroxide and 3-12 moles ammonia per mole alpha -amino nitrile.
申请公布号 EP0232562(A1) 申请公布日期 1987.08.19
申请号 EP19860202259 申请日期 1986.12.15
申请人 STAMICARBON B.V. 发明人 BOESTEN, WIHELMUS H. J.;KAMPHUIS, JOHAN
分类号 C07D209/20;B01J27/00;C07C67/00;C07C231/00;C07C231/06;C07C237/00;C07C237/06;C07C237/16;C07C237/20;C07D233/61;C07D233/64;(IPC1-7):C07C102/08 主分类号 C07D209/20
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