摘要 |
NEW MATERIAL:A compound shown by formula I (R<1>-R<3> are 1-4C alkyl, 1-2C halogen-substituted alkyl, 1-4C alkoxy, halogen or nitro; l, m and n are 0-4; R is phenyl or naphthyl; t is 1-5). EXAMPLE:1-Benzyl-3, 3-dimethylspiro{indoline-2,3'-[ 3H ]-phenanthro[9,10-b](1,4) oxazine}. USE:A photochromic material for printing, photochromic material for optical element, photochromic material for recording material and photochromic mate rial for clothes and ornaments. PREPARATION:A 2-methyleneindoline compound (e.g., 1-benzyl-3,3-dimethyl-2- methyleneindoline, etc.,) shown by formula II is reacted with a 10-nitroso-9- phenanthrol compound shown by formula III. |