1. A process for preparing aldehydes by the reaction of alphatic olefins having 2 to 12 carbon atoms with carbon monoxide in liquid phase in the presence of water, rhodium in metallic form or as a compound and the water-soluble salt of a sulfonated or carboxylated triaryl phosphine, characterised in that 0.5 to 4.0% by volume carbon dioxide, related to the total gas mixture, is added to the mixture of carbon monoxide and hydrogen.
申请公布号
EP0160249(A3)
申请公布日期
1987.05.27
申请号
EP19850104606
申请日期
1985.04.16
申请人
RUHRCHEMIE AKTIENGESELLSCHAFT
发明人
CORNILS, BOY, DR. DIPL.-CHEM.;KONKOL, WERNER, DR. DIPL.-CHEM.;BACH, HANSWILHELM, DR. DIPL.-CHEM.;DAMBKES, GEORG, DR. DIPL.-CHEM.;GICK, WILHELM, DR. DIPL.-CHEM.;WIEBUS, ERNST;BAHRMANN, HELMUT, DR. DIPL.-CHEM.