发明名称 PRODUCTION OF ALKENYLSUCCINIC ANHYDRIDE
摘要 PURPOSE:To obtain the titled high-purity compound useful as a sizing agent, resin improver, plasticizer, additive for lubricating oil, rust preventive, etc., in high yield, by reacting an alpha-olefin with maleic anhydride in the presence of a polymerization inhibitor such as a metallic salt of a dialkyldithiocarbamic acid, etc. CONSTITUTION:(A) An alpha-olefin (>=4C straight-chain olefin such as octadecene-1, etc.,) is reacted with (B) maleic anhydride in a feed ratio of preferably 1.1:1.0-1.8:1.0 in the presence of at least one polymerization inhibitor selected from a metallic salt of a dialkyldithiocarbamic acid (e.g., copper dimethyldithiocarbamate, etc.,) and a naphthol (e.g., alpha-naphthol, etc.,) at 200-250 deg.C to give the aimed succinic acid. The amount of the polymerization inhibitor used is preferably 10-10,000ppm.
申请公布号 JPS62106091(A) 申请公布日期 1987.05.16
申请号 JP19850244195 申请日期 1985.11.01
申请人 NIPPON SHOKUBAI KAGAKU KOGYO CO LTD 发明人 SONODA TAKEZO;UDA KIMIO;YOSHIDA OSAMU
分类号 C07D307/60 主分类号 C07D307/60
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