Hydrocarbon conversion catalyst and process for selectively making middle distillates.

摘要

A hydrocarbon conversion catalyst useful for converting hydrocarbon feeds to midbarrel products is prepared by extruding a mixture of a porous, inorganic refractory oxide component and a crystalline aluminosilicate zeolite having cracking activity to from extrudates which are broken into particles normally ranging in length between 1.5 and 12 mm (between 1/16 and 1/2 inch). The extruded particles are then calcined in the presence of added steam at a water vapor partial pressure greater than about 1.4 kPa (2.0 p.s.i.a.), preferably greater than about 34.5 kPa (5.0 p.s.i.a.). The calcination step is carried out in the presence of sufficient added steam for a sufficient amount of time at a sufficient temperature to convert the crystalline aluminosilicate zeolite in the extrudates into an ultrahydrophobic zeolite having a unit cell size between about 24.20 and about 24.45 Angstroms and a sorptive capacity for water vapor less than about 5 weight percent of the zeolite at 25 DEG C and a p/p DEG value of 0.10.