发明名称 |
Rhodium on carbon catalyst. |
摘要 |
<p>A particulate catalyst composition suitable for purification of terephthalic acid under reducing conditions and a method of preparation of such catalyst are disclosed. The catalyst composition includes catalytically active rhodium on a porous, granular, carbonaceous support material having a surface area of at least about 600 cm²/gram. Rhodium is present in an amount of about 0.01 to about 2 weight percent, based on the total weight of dry catalyst composition and calculated as elemental metal. In the presence of hydrogen, this catalyst exhibits a reduced terephthalic acid decomposition rate that is comparable to that for a palladium-on-carbon catalyst having the same catalyst metal loading. The catalyst is prepared by contacting a carbonaceous support material having a surface area of at least 600m²/gm and a pH value in its aqueous suspension of 9-11 with an aqueous rhodium salt solution having a pH of 1-4. </p> |
申请公布号 |
EP0219288(A1) |
申请公布日期 |
1987.04.22 |
申请号 |
EP19860307678 |
申请日期 |
1986.10.03 |
申请人 |
AMOCO CORPORATION |
发明人 |
SCHROEDER, HOBE;WITTMAN, RICKY LYNN |
分类号 |
C07C63/26;B01J23/46;B01J32/00;C07B61/00;C07C51/00;C07C51/47;C07C67/00;(IPC1-7):B01J23/46 |
主分类号 |
C07C63/26 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|