发明名称 |
Catalyst system for amine transalkylation |
摘要 |
In the transalkylation of tertiary amines, unexpected higher yields are achieved requiring substantially less catalyst and much shorter reaction times at lower reaction temperatures using a homogeneous catalyst in the presence of an alcohol solvent and carbon monoxide. The process may be exemplified by reacting triethylamine and tripropylamine in the presence of a homogeneous triosmiumdodecacarbonyl catalyst, ethanol, and carbon monoxide to prepare diethylpropylamine and ethyldipropylamine.
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申请公布号 |
US4645837(A) |
申请公布日期 |
1987.02.24 |
申请号 |
US19840668298 |
申请日期 |
1984.11.05 |
申请人 |
SRI INTERNATIONAL |
发明人 |
LAINE, RICHARD M.;SHVO, YOUVAL |
分类号 |
C07C209/64;(IPC1-7):C07D295/12;C07C87/127;C07C87/20;C07D295/02 |
主分类号 |
C07C209/64 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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