发明名称 |
Cellulose dope, process for preparation and method for application thereof |
摘要 |
Described is a cellulose dope which is an aqueous alkali solution containing substantially at least 3% by weight of cellulose having a degree of polymerization of at least 100, wherein in the 13C-NMR spectrum of the cellulose, the C4-position carbon peak is found at a magnetic field higher by at least 7 ppm than the magnetic field of the C4-position carbon peak of solid cellulose attributed to the strong intramolecular hydrogen bond. This dope is prepared by maintaining a mixture comprising 100 weight parts of cellulose, which may have any crystal form, and 10 to 1000 weight parts of a hydrogen bond-cleaving solution at 100 DEG C. to 350 DEG C. under a pressure of 10 to 250 atmospheres, promptly exposing the mixture to the ambient atmosphere, mixing the resulting cellulose with an aqueous alkali solution maintained at a temperature not higher than 50 DEG C., and then stirring the mixture at a temperature not higher than 10 DEG C. to dissolve the cellulose in the aqueous alkali solution. The dope may be used for the manufacture of a shaped article or for coating.
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申请公布号 |
US4634470(A) |
申请公布日期 |
1987.01.06 |
申请号 |
US19840675762 |
申请日期 |
1984.11.28 |
申请人 |
ASAHI KASEI KOGYO KABUSHIKI KAISHA |
发明人 |
KAMIDE, KENJI;OKAJIMA, KUNIHIKO |
分类号 |
D06M15/05;C08B1/00;C08B16/00;C08L1/02;D06M101/00;D06M101/02;D06M101/06;D06M101/08;D06M101/16;D06M101/18;D06M101/30;D06M101/32;D06M101/34;(IPC1-7):C08L1/00 |
主分类号 |
D06M15/05 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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