| 摘要 |
A process is described for the formation of high purity alumina from Bayer Process alumina trihydrate (gibbsite). The solid hydrated alumina is reacted with concentrated HCl to cause partial or complete conversion to aluminum chloride hexahydrate (ACH). The ACH or mixture of ACH and unreacted hydrated alumina is recovered as a solid and calcined in a single or multistage calcination to high purity alumina. Soda contents in the product anhydrous alumina can be reduced by 98% or greater. Contents of other impurities, such as silica, iron, magnesium, etc., are also markedly reduced. Different degrees of impurity reduction can be obtained by controlling the degree of conversion of the hydrated alumina to ACH and by recycling and treating the acid after solid/liquid separation. The purified products find use in the specialty ceramics field, as catalyst supports, as adsorbents, in electronic components, in prosthetic devices or other applications in which alumina of controlled degrees of purity offers an advantage.
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