PVC membrane with reduced plasticizer migration

摘要

The present invention relates to a membrane comprising a bulkhead layer, wherein more than 50% by weight of the bulkhead layer is composed of PVC, and a barrier layer. The barrier layer can, on the one hand, be a barrier layer S1, wherein the barrier layer S1 has a polyvinyl alcohol layer comprising more than 50% by weight of copolymer PA, which is connected to the bulkhead layer by a polyurethane layer, wherein more than 10% by weight of the polyurethane layer is composed of polyurethane PUR. The barrier layer can, on the other hand, be a barrier layer S2, wherein the barrier layer S2 has a composition comprising 5-50% by weight of polyurethane PUR and 50-95% by weight of copolymer PA. The membranes according to the invention have significantly lower plasticizer migration compared to the membranes of the prior art and are distinguished by improved resistance to aging, particularly as regards the adherence of the barrier layer on the bulkhead layer, and imperviousness to damp.

主权项

1. A membrane comprising:
a sealing layer comprising more than 50% by weight of PVC in relation to the total weight of the sealing layer; and a barrier layer S2 comprising 5-50% by weight of polyurethane PUR and 50-95% by weight copolymer PA, wherein the polyurethane PUR has at least one nucleophilic functional group, which is selected from the group consisting of hydroxyl group, carboxyl group, sulfonate group and phosphate group, and the copolymer PA is an ethylene vinyl alcohol copolymer, and wherein the sealing layer and the barrier layer are in direct contact.