| 摘要 |
Reactive antioxidant compounds, able to stabilise organic polymers, contain in their molecule a sterically hindered phenolic group and a hydrolysable silyl function. …<??>In stabilising organic polymers, said reactive antioxidant compounds can be hydrolysed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilising structures. These latter are added in stabilising quantities to the polymer to be stablised. …<??>According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilised. …<??>According to a further embodiment, the reactive antioxidant compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxly groups. …<??>According to a further embodiment, the reactive antioxidant compound is made to interact with the polymer so that the stabilising compound becomes chemically bonded to the polymer chains. …<??>In all cases, stabilised polymers are obtained containing the antioxidant compound in a form which is not removable from the polymer. …<??>The process for preparing the reactive antioxidant compounds and for preparing the stabilised polymer compositions are also described. |
