| 摘要 |
<p>Novel compounds have been discovered in which a bis compound of a polysubstituted 2-keto-1,4-diazacycloalkane ("2KDZC") provides a diurethane bridge so as to form an oligomeric 2KDZCurethane ("2K-U" oligomer) having from 2 to about 15 repeating units; the bis compound bridge itself consists essentially of two distally linked polysubstituted 2KDZC moieties, and the 2K-U oligomer formed consists essentially of two 2KDZC moieties linked through their N1 atoms, which moieties in turn are distally linked to urethane groups through the N atoms of the 2KDZC. Such 2K-U oligomers unexpectedly contain a self-limiting number of 2K-U repeating units which happens to provide 2K-U oligomers which are desirable and highly effective u-v light stabilizers in organic materials; more specifically, this invention provides a novel class of polymeric hindered amine-urethane derivatives, particularly piperazinone bis compounds which may be distally linked to each other in a single step reaction utilizing an appropriately substituted diamine, a haloform such as bromoform or chlorform, in one of several known syntheses for making 2-keto-diazacycloalkanones, some of which syntheses may preferably utilize a phase transfer catalyst; this bis compound may then be hydroxyalkylated and reacted with an appropriate diisocyanate.</p> |
