发明名称 3,3-DIMETHYL-SPIRO(INDOLINO-2,3'-NAPHTHO(2,1-B)-(1,4) OXAZINE) COMPOUND
摘要 NEW MATERIAL:The compound of formula I (n is 1-4; R<1> is alkyl; R<2>-R<5> are H, halogen, alkyl, alkoxy or alkoxycarbonyl). EXAMPLE:The compound of formula II. USE:Various recording and memory materials, copying materials, photo-sensitive materials for printing use, materials sensitive to laser beam, photosensitive materials for phototypography, optical filters, masking materials, actinometer, materials for display, etc. It has photochromic property. PREPARATION:The 2,3,3-trimethylindolenine derivative of formula III is made to react with p-toluenesulfonic acid ester of formula IV at 130-150 deg.C preferably in the absence of solvents and the reaction product is made to react with the 1-nitroso-2-naphthol derivative of formula V in a solvent (preferably ethanol, etc.) in the presence of piperidine catalyst at 40-120 deg.C.
申请公布号 JPS61263982(A) 申请公布日期 1986.11.21
申请号 JP19850012191 申请日期 1985.01.25
申请人 MITSUBISHI CHEM IND LTD 发明人 IRIE MASAHIRO;MAEDA SHUICHI
分类号 C07D498/10;C07D513/10;C09K9/02;G02F1/17;G03C1/685;G03C1/73 主分类号 C07D498/10
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