发明名称 |
Carbonylation of allylic ethers to esters |
摘要 |
A method is disclosed for the production of esters by reaction of an alkyl acyclic allylic ether such as 8-methoxy-1,6-octadiene with carbon monoxide in the presence of a halide of nickel, cobalt or iron as a catalyst and especially nickel iodide for the production of esters. Carbonylation of 8-methoxy-1,6-octadiene results in the production of methyl-3,8-nonadienoate; 2-(carbomethoxymethyl)-vinylcyclopentane; 2-(carbomethoxymethyl)-6-vinylcyclohexanone and 2-carbomethoxymethylbicyclo(3.3.0)-octan-3-one.
|
申请公布号 |
US4622416(A) |
申请公布日期 |
1986.11.11 |
申请号 |
US19850725290 |
申请日期 |
1985.04.19 |
申请人 |
NATIONAL DISTILLERS AND CHEMICAL CORPORATION |
发明人 |
HANES, RONNIE M.;BAUGH, WILLIAM D. |
分类号 |
C07C67/36;(IPC1-7):C07C67/36;C11C3/04 |
主分类号 |
C07C67/36 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|