发明名称 Catalytic asymmetric epoxidation.
摘要 <p>Improved method for epoxidation of ethylenic alcohols is provided employing catalytic amounts of a tianium-glycol catalyst and a peroxide under mild conditions which provide for the continuous maintenance of an anhydrous medium during catalyst formation and during the course of the reaction. Conveniently, molecular sieves may be employed.</p>
申请公布号 EP0197766(A2) 申请公布日期 1986.10.15
申请号 EP19860302466 申请日期 1986.04.03
申请人 MASSACHUSETTS INSTITUTE OF TECHNOLOGY 发明人 HANSON, ROBERT M.;KO, SOO YOUNG;SHARPLESS, KARL B.
分类号 B01J31/00;B01J31/22;C07B61/00;C07D301/19;C07D303/14;(IPC1-7):C07D303/14 主分类号 B01J31/00
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