发明名称 PRODUCTION OF PROPYLENE BLOCK COPOLYMER
摘要 PURPOSE:To obtain a block copolymer having a small amount of formed low crystalline part, slightly causing aggregation and anchorage, having improved low-temperature impact resistance, by carrying out block copolymerization by specific two processes in the presence of a catalyst obtained by combining three components. CONSTITUTION:A propylene-ethylene block copolymer is obtained by polymerization of the following two processes in the presence of catalyst obtained by combining three components of (A) a solid composition comprising magnesium, titanium and a halogen as essential components, (B) an organoaluminum compound and, (C) an amine compound having steric hindrance. (i) Propylene alone or a mixture of propylene/ethylene is polymerized at one stage or multiple stages to form 60-95wt% based on the final amount of polymer of a propylene polymer or a propylene-ethylene copolymer containing <=7wt% ethylene. (ii) A mixture of propylene/ethylene is polymerized at one stage or multiple stages to form a propylene-ethylene copolymer containing 20-100wt% ethylene.
申请公布号 JPS61218615(A) 申请公布日期 1986.09.29
申请号 JP19850059139 申请日期 1985.03.23
申请人 MITSUBISHI PETROCHEM CO LTD 发明人 NEGAMI YASUHIKO;MATSUI AKIRA;NIWA TAKASHI;SAKURAI HIDEO
分类号 C08F297/00;C08F4/16;C08F4/52;C08F4/60;C08F4/64;C08F297/08 主分类号 C08F297/00
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