COMPOSITIONS FOR FORMING POLY(OXAZOLIDONE/URETHANE) THERMOSETS AND PRODUCTS THEREFROM

摘要

COMPOSITIONS FOR FORMING POLY(OXAZOLIDONE/ URETHANE) THERMOSETS AND PRODUCTS THEREFROM Reaction of a diepoxide with a mono-, or, preferably, dicarboxylic acid yields a prepolymer having both hydroxy and epoxy groups. This prepolymer, when reacted with a polyisocyanate, yields a poly(oxazolidone/urethane) thermoset composition which is substantially free of isocyanurate linkages. The thermoset contains oxazolidone linkages in its backbone which are separated from one another by ester linkages. Urethane linkages are present in side chains attached to the polymer backbone of the thermoset.