发明名称 HALOTOLAN DERIVATIVE
摘要 NEW MATERIAL:A compound shown by the formula I (R and R' are 1-10C straight-chain alkyl, or straight-chain alkoxy; X is halogen). EXAMPLE:A compound shown by the formula V. USE:An electro-optical display material (liquid crystal) having high DELTAn (anisotropy of refractive index) and improved characteristics capable of adjusting easily DELTAn by blending it with an existing liquid crystal composition. PREPARATION:A compound shown by the formula II is reacted with iodine and periodic acid dihydrate in acetic acid, water, or carbon tetrachloride to give a compound shown by the formula III, which is reacted with a compound shown by the formula V in the presence of dichloro-bis(triphenylphosphine) palladium (II) and cuprous iodide as a catalyst in diethylamine or N,N- dimethylformamide, to give a compound shown by the formula I.
申请公布号 JPS61197533(A) 申请公布日期 1986.09.01
申请号 JP19850037023 申请日期 1985.02.26
申请人 DAINIPPON INK & CHEM INC 发明人 TAKATSU HARUYOSHI;TANAKA YASUYUKI;TAKEUCHI KIYOBUMI
分类号 C07C17/26;C07C17/00;C07C17/12;C07C25/13;C07C25/24;C07C41/00;C07C41/30;C07C43/225;C07C67/00 主分类号 C07C17/26
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