发明名称 PRODUCTION OF POLYFUNCTIONAL ESTER
摘要 PURPOSE:To obtain a polyfunctional ester having low coloring industrially advantageously, by reacting methacrylic acid or acrylic acid with trimethylolpropane in the presence of both a solid decoloring agent such as activated alumina, etc., and an acid catalyst. CONSTITUTION:Methacrylic acid or acrylic acid is reacted with trimethylolpropane in the presence of preferably 0.01-5wt% (especially 0.1-2wt%) based on theoretical formation ester of a solid decoloring agent such as activated alumina, Molecular Sieve (especially preferably activated clay, active carbon, etc.) and an acid catalyst such as sulfuric acid, p- toluenesulfonic acid, etc., to give trimethylolpropane methacrylate or acrylate. By this method, the titled compound having a number of colors of <=APHA 30 and low coloring can be obtained by a simple operation.
申请公布号 JPS61165349(A) 申请公布日期 1986.07.26
申请号 JP19850004846 申请日期 1985.01.17
申请人 MITSUBISHI RAYON CO LTD 发明人 TAKEDA HITOSHI;SATO TOSHIHIRO;OTA HIDENORI
分类号 B01J31/02;C07B61/00;C07C67/08;C07C69/54 主分类号 B01J31/02
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