摘要 |
A tough Si3N4 ceramic composite is provided by incorporating a ternary oxide additive containing hafnia, titania and zirconia. The ternary oxide additive consists essentially of 60 to 85 mole percent hafnia, 10 to 30 mole percent titania and 10 to 30 mole percent zirconia, and is added to the Si3N4 in a proportion ranging from about 10 to about 50%, by volume of ternary oxide additive, based on the overall composition. The ceramic composites are prepared by providing a mixture of the Si3N4 and the ternary oxide additive, forming the mixture into a predetermined shape, e.g. by cold pressing, and sintering the shape at an appropriate temperature, to solidify and densify the shape.
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