Oxide whisker growth on contaminated aluminium-containing stainless steel foil.

摘要

In aluminium-containing stainless steel foil, the presence of magnesium impurity in an amount greater than about 0.002 weight percent has been found to inhibit formation of a preferred oxide surface layer thereon characterized by multitudinous oxide whiskers of a type suitable for tightly bonding an applied coating. A method for purifying magnesium-contaminated foil comprises heating the foil to selectively vaporize the magnesium while avoiding incipient melting of the base alloy, preferably between 1000 DEG C and 1150 DEG C. The magnesium vapors escape into a suitable ambient phase such as a vacuum or a dry hydrogen gas. Thereafter, the foil is oxidized under conditions effective to produce the desired whiskers. A preferred steel is composed of an iron-base alloy comprising about 15 to 25 weight percent chromium and 3 to 6 weight percent aluminium, and optionally may contain cerium or yttrium in an amount effective to promote oxide adherence.