发明名称 PRODUCTION OF 2, 2'-METHYLENEBIS(4-SUBSTITUTED-6 BENZOTRIAZOLYLPHENZOL
摘要 PURPOSE:To obtain the titled compound, by reacting benotriazolylphenol with an amine and a formamide to give a Mannich base compound, dimerizing it or reacting it with the benzotriazolylphenol. CONSTITUTION:1 mol 4-substituted-6-benzotriazolylphenol shown by the formula I (R is alkyl, or arylalkyl; X is H or substituent group inactive to the reaction) is reacted with 0.5-1.5 mol amine (e.g., primary amine, secondary amine, or morpholine) and 0.5-1.5 mol formaldehyde to give a Mannich base compound shown by the formula II (R1 and R2 is lower alkyl, or R1, R2, and N form ring), which is reacted with the compound shown by the formula I, or the com pound shown by the formula II is dimerized to give a compound shown by the formula III. Both the reaction temperatures are 30-150 deg.C.
申请公布号 JPS61115073(A) 申请公布日期 1986.06.02
申请号 JP19840236290 申请日期 1984.11.09
申请人 ADEKA ARGUS CHEM CO LTD 发明人 KUBOTA NAOHIRO;NISHIMURA JUN
分类号 C07D249/20 主分类号 C07D249/20
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