| 摘要 |
Electrically conductive polymeric systems having electrical conductivities greater than 10-4 S/cm are prepared by a method wherein a polyarylene compound which contains one or more chain members of the formula <IMAGE> where n is greater than 1, preferably from 5 to 50, R is a nitrile, acid amide, carboxyl or ester group, R1 and R2 are each hydrogen or a nitrile, acid amide, carboxyl or ester group, with the proviso that in each case one of the radicals R1 and R2 is hydrogen and the other is a nitrile, acid amide, carboxyl or ester group, and Y is an aromatic radical, preferably phenylene, is doped, in the absence of moisture and oxygen, with from 0.03 to 0.9 mole percent of an electron-attracting or electron-donating complexing agent. The resulting electrically conductive polymeric systems are useful in the electrical industry for the production of solar cells, for converting and fixing electromagnetic radiation and for the production of electrical and magnetic switches and electrical storage devices, and can be used for the antistatic treatment of plastics. |
