发明名称 |
Process for the preparation of hydroxybenzaldehydes |
摘要 |
In a Reimer-Tiemann reaction for the preparation of a mixture of two hydroxybenzaldehydes (i.e., salicylaldehyde and p-hydroxybenzaldehyde) by reacting phenol with chloroform and an aqueous alkali solution in a heterogeneous system, the two hydroxybenzaldehydes can be prepared in a controlled formation ratio, yield and reaction rate depending upon the conditions used when the reaction is carried out in the presence of a phase transfer catalyst selected from the group consisting of a cationic type phase transfer catalyst, an amphoteric type phase transfer catalyst and an anionic type phase transfer catalyst.
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申请公布号 |
US4584410(A) |
申请公布日期 |
1986.04.22 |
申请号 |
US19840670847 |
申请日期 |
1984.11.13 |
申请人 |
SUMITOMO CHEMICAL CO., LTD. |
发明人 |
HAMADA, KAZUHIKO;SUZUKAMO, GOHFU;MASUKO, FUJIO;NAKAMURA, MAKOTO |
分类号 |
C07C47/565;B01J31/02;C07B61/00;C07C45/00;(IPC1-7):C07C45/45 |
主分类号 |
C07C47/565 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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