发明名称 |
Continuous process for the production of aldehydes by hydroformylation of olefins |
摘要 |
A continuous hydroformylation process for the production of an aldehyde by hydroformylation of an olefin comprises: providing a hydroformylation zone containing a charge of a liquid reaction medium having dissolved therein (a) a complex rhodium hydroformylation catalyst comprising rhodium in complex combination with carbon monoxide and with a cyclic phosphite having a phosphorus atom linked to three oxygen atoms at least two of which form together with the phosphorus atom part of a ring and (b) a ligand stabilizing amount of a tertiary amine; supplying said olefin to the hydroformylation zone; maintaining temperature and pressure conditions in the hydroformylation zone conducive to hydroformylation of the olefin; supplying make-up hydrogen and carbon monoxide to the hydroformylation zone; and recovering from the liquid hydroformylation medium a hydroformylation product comprising at least one aldehyde. |
申请公布号 |
US4567306(A) |
申请公布日期 |
1986.01.28 |
申请号 |
US19840680834 |
申请日期 |
1984.12.12 |
申请人 |
DAVY MCKEE (LONDON) LIMITED |
发明人 |
DENNIS, ALAN J.;HARRISON, GEORGE E.;WYBER, JAMES P. |
分类号 |
B01J31/00;B01J31/18;C07B61/00;C07C45/00;C07C45/50;C07C47/02;C07C67/00;C07F9/6574;(IPC1-7):C07C45/50 |
主分类号 |
B01J31/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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